pH/Ion Meter BMET-503

pH/Ion Meter BMET-503

  • Sea, Air, Door to Door Shipping
  • 1 Year Warranty
  • US & European Standards
An ion meter is a device which with the aid of electrochemical activity of ion electrodes measures the concentration of ions in a solution. It works by the means of selective ion electrodes and measuring ion activity capability of sensitive membrane of a measuring devices. A sensor electrode and a reference electrode are used to measure the ion concentration in a solution.
    Specification Features
    pH: 
          Range-2.00 to 20.00 pH
          Resolution0.1, 0.01 pH
          Accuracy± 0.01 pH
          Calibration PointsUp to 5
          Standard CustomizationYes
          Standard RecognitionNIST, GB and DIN buffers
    mV: 
          Range-2000.0 to 2000.0 mV
          Resolution0.1 mV
          Accuracy± 0.3 mV or ± 0.1 % of reading whichever is greater
    pX: 
          Range- 2.00 to 20.00
          Resolution0.1, 0.01 pX
          Accuracy±0.02 pX
          Calibration PointsUp to 5
    ISE: 
          Range1E-9 to 9.999E9
          Unitmol/L, mmol/L, g/L, mg/L, μg/L, ppm
          ResolutionUp to 4 significant digits
          Accuracy± 0.5 %
          Calibration PointsUp to 5
    Temperature: 
          Range-5 to 110 °C, 23 to 230 °F
          Unit°C, °F
          Resolution0.1
          Accuracy± 0.2
    Measurement: 
          Reading ModeAutoRead( Fast, Medium,Slow), Timed, Continuous
          Reading PromptsReading, Stable, Locked
          Temp. CompensationATC, MTC
    Data Management: 
          Data Storage500 results each
          GLP FeaturesYes
    Inputs: 
          pH ElectrodeBNC(Q9)
          Temp./DO Probe4-pin aviation connector
    Outputs: 
          USBPC
          RS 232printer
    Display Options: 
          BacklightYes
          Auto Shut-down1~60 min, off
          IP RatingIP54
          Date and TimeYes
    General: 
          PowerAC Adapter, 100-240 V AC input, DC 9 V output
          Dimensions242x195x68 mm
          Weight900 g(1.98 lb)
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    Operating Manual for BMET-503

    Download Operating Manual PDF

    1. Introduction
        1.1 Introduction
        1.2 Technical Specification
        1.3 Function Introduction
    2. Safety Notices
    3. Terms Explanation
    4. Overview and Installation
        4.1 Overview
        4.2 Instrument Installation
    5. Instrument Operation
        5.1 Switch On/Off
        5.2 Screen Icons
        5.3 Function Key
        5.4 Instrument settings
        5.5 pH Measurement
        5.6 Ion measurement
        5.7 Data Management
    6. Maintenance/Troubleshooting
        6.1 Meter Maintenance
        6.2 Electrodes Maintenance
        6.3 Troubleshooting
    7. Technical Supports
    8. Appendixes

    1. Introduction

    1.1 Introduction

    BMET-503 pH/Ion meter is a newly designed functional instrument, support pH, potential, ion concentration measurement, can be widely used in universities, environmental protection, medicine, food, sanitation, geological prospecting, metallurgy, ocean exploration and other fields measurements for acid rain detection, industrial wastewater, surface water, drinking water, beverages, daily chemical products, textiles and other related industries.
    • General Features
    • High resolution LCD display, 5.7 inches.
    • Multi-reading feature allows auto-read, timed-read and continuous-read.
    • Automatic/Manual temperature compensation ensures accurate results.
    • Auto-hold feature senses and locks the measurement endpoint.
    • Data Storage 500 sets (GLP-compliant).
    • Support for USB or RS-232 communication.
    • Reset feature automatically resumes all settings back to factory default options.
    • IP54 waterproof.
    pH
    • 1-5 points calibration with Standard Recognition.
    • Selectable pH buffer groups, including NIST, DIN, GB and USA.
    • Automatic electrode diagnosis with pH slope and offset display.
    Ion
    • 1-5 points calibration.
    • Selectable measurement unit, including μg/L, mg/L, g/L, mmol/L, pX, ppm, and ppb.
    • Multi-measurement modes are supported, including Direct Reading mode, Standard Addition mode, Sample Addition mode and GRAN mode.
    • Over 10 methods are built-in, including F-, Cl-, Br-, I-, NO3-, BF4-, NH4+, K+, Na+, Ca2+, Cu2+, Pb2+, Ag+ and etc., user-defined method is supported.

    1.2 Technical Specification

    Instrument Specifications

    ModelBMET-503
    pH/pX level0.01 pH/pX
    mVRange(-2000.0~ 2000.0)mV
    Resolution0.1mV
    Accuracy±0.1% or ±0.3 mV
    Repeatability0.5mV
    Input Current≤1×10 -12 A
    Input Impedance≥1×10 12 Ω
    pHRange(-2.00~ 20.00)pH
    Resolution0.01pH
    Accuracy±0.01pH
    Repeatability0.005pH
    Measurement Accuracy±0.02pH
    Measurement Repeatability0.01pH
    pXRange(-2.00~ 20.00)pX
    Resolution0.01pX
    Accuracy±0.01pX
    Repeatability0.005pX
    Measurement Accuracy±0.02pX
    Measurement Repeatability0.01pX
    Ion concentrationRange(1E-9~9.999E9),
    mol/L, mmol/L, g/L, mg/L, μg/L,
    ppm, ppb
    Resolution4 significant digits
    Measurement Accuracy±0.5%
    TemperatureRange(-5.0~ 110.0)℃
    Resolution0.1℃
    Accuracy±0.2℃
    Instrument indication error±0.4℃(0.0℃~60.0℃),
    ±1.0℃(Else)
    Work environmentAmbient temperature: (0~ 40)℃
    Relative humidity: not more than 85%
    Dimensions (L×B×H), weight (kg)242mm×195mm×68mm,
    0.9kg
    Power supplyPower adapter
    (Input AC 100~240V, Output DC 9V)

    Table 1

    1.3 Function Introduction

    Functions Specification

    FeaturesExplanation
    Basic FunctionLanguagesEnglish
    Backlight adjustment
    Automatic diagnostics
    Factory reset
    Default parameter
    Prompt Sound
    Time settings
    Power failure protection
    Firmware upgrade
    Anti-interference automatic recovery
    Automatic shutdown
    ProtectionIP54
    Reading functionBalance condition setting
    When balance state reached, display the reading stability indicator
    End point judgment/reading mode
    Sample ID input
    Data ManagementStorage500 sets
    View
    Delete
    Data ManagementGLP
    Communications and external devicesPrinterSerial Printer
    Content and format customizationStandard, GLP, Custom format
    Communications and external devicesPC
    pH/mV
    Measurement
    pH electrode status/performanceSlope
    Multi-point calibration5 points
    Automatic standard solutions recognition3 groups
    Standards customization
    Standard groups customization1 group
    Automatic temperature compensation
    Manual temperature compensation
    pH electrode diagnostics
    pX/ISE
    Measurement
    Multi-point calibration5 points
    Optional units
    Measurement modeDirect reading concentration method
    Built-in ions methods
    Ions customization
    Temperature MeasurementTemperature units℃ , ℉

    Table 2

    2. Safety Notices

    Please read the entire contents of this manual carefully before use, and please keep this manual properly. The user MUST use the instrument following this manual to avoid damage to the user and equipment.
    Before using the meter, READ the following notes:
    • DO NOT disassemble the device for inspection or repair.
    • To prevent electric shock or damage to the device, do not place cables and connectors in any liquid, wet or corrosive environment.
    • Please use the defaulted power adapter, Do not use it if the power cord is damaged (the wire is exposed or broken).
    • Do not use in flammable and explosive environments.
    • Do not use if the user finds any abnormalities such as damage or deformation of the device.
    The following identifier will be used in this manual.
    TIPS:
    Tips help users to use the meter.

    3. Terms Explanation

    • pH/pX
    • pH/pX Slope: The amount of potential change generated by each 1 pH/pX change, expressed in mV/pH or by 100% Theoretical Slope (PTS). pX = - log[X], where [X] means molar concentration (mol/L) of X ions.
    • E0 of pH: Also known as "zero potential", it usually refers to the potential value at a pH of 7.
    • One-point calibration: Calibration with a standard solution.
    • Two-point calibration: Calibration with two standard solutions.
    • Multi-point calibration: Calibration with more than two standard solutions.

    4. Overview and Installation

    4.1 Overview


    Figure 1
    Overview-Front View

    Figure 2
    Overview-Back View

    Figure 3
    Electrodes and connectors

    Connector Specifications

    ConnectorElectrode type
    BNC(Q9)pH, ion selective electrode
    BananaReference electrode

    Table 3

    4.2 Instrument Installation

    4.2.1 Electrodes Stand Installation

    Figure 4
    Electrode Stand Installation
    Installation:
    1) Pull out the electrode holder fixing plate on the right side of the instrument.
    2) Insert the multifunctional electrode holder support (as Figure 4-4) into the vertical shaft of the multifunctional electrode holder drawer.
    3) Tighten the set screw on the lower part of the electrode holder’s pole.

    4.2.2 Electrodes Connection
    Push the Fluoride ion electrode into the electrode holder. Find the measuring electrode socket on the back of the instrument, unplug the Q9 shorting circuit connector. Then, insert the fluoride ion electrode connector into the measuring electrode socket. When other electrodes are used as required, Insert the electrode connector to the corresponding socket on the back of the instrument in the same way as above.

    5. Instrument Operation

    5.1 Switch On/Off

    After connecting the power adapter and installing the electrode stand and electrode, press to switch on the meter. The startup screen shows software version and other related information. After the self-test program, the screen turns to the homepage and the meter is ready to measure.
    The instrument uses touch keys as operation and control equipment, and is equipped with 8 keys in total. You can complete the corresponding operations by pressing the corresponding function keys.
    Also press and hold the key for more than 3 seconds and release to shut down.

    5.2 Screen Icons


    Figure 5
    Screen icons explanation
    1 Instrument model. 2 System time. 3 Measurement parameters &Reading status. 4 Main measurement box. 5 Calibration information. 6 User ID. 7 Sample ID. 8 Operation tips. 9 Soft function keys.
    The instrument displays symbol identification that has the following functional implications:
    Symbol Explanation

    No.SymbolExplanation
    1Reading status, display the measurement status of reading, stable, locked, each indicates that the processing, stable, and reading completed.
    2The percentage slope of the pH electrode calibration data.
    3The time of calibration
    4Measuring ions
    5Calibration point
    6Standard solution for pH calibration
    7Standard solution for ion calibration
    8Automatic temperature compensation
    9Manual temperature compensation
    10User ID
    11Sample ID
    12Operation tips
    13The Standard buffer solution for calibration

    Table 4

    5.3 Function Key


    Figure 6
    Function keys explanation
    Key Function Explanation

    No.KeyExplanationNote
    1PowerPress to switch on/off
    2SettingSet the parameters and settings
    3CancelCancel the operation
    4EnterConfirm the option
    5F1Function key, Corresponds to the function options on the screen
    6F2Function key, Corresponds to the function options on the screen
    7F3Function key, Corresponds to the function options on the screen
    8F4Soft function keys, corresponding to the functions on the screen

    Table 5

    5.4 Instrument settings

    In the measuring, users can set the instrument parameters by pressing "Setting" to set the measuring parameters.

    5.4.1 Tutorial setting
    For the first use, please follow the guide to settings the measurement parameters. After all the settings, press the "Enter" to return to the previous page.

    5.4.2 Measurement parameter settings
    It could select one measurement parameter from pH, pX/ISE and Ion Conc.

    5.4.3 Reading Mode Settings
    The meter provides three reading modes, including continuous reading, auto reading, and timed reading.
    • Continuous reading: The instrument displays real-time measurement results. User can end the measurement at any time and save the last result.
    • Auto-reading: The measurement reached the balance, and the meter locked the reading result. The meter offers "Fast", "Medium", "Strict" and "Custom" four options for endpoint detection conditions.
    • Time reading method: Timed Reading contains two kinds of timed reading methods: "Interval Measurement" and "Timed Measurement". "Interval Measurement" provide measurement results at interval time and "Timed Measurement" provide measurement result after a set time.
    Reading Parameters Settings

    Stability TypepHpX/Ion concentration
    FastStable time4s4s
    Fluctuation1mV0.6mV
    MediumStable time6s8s
    Fluctuation0.5mV0.2mV
    StrictStable time8s12s
    Fluctuation0.1mV0.1mV
    Custom
    (Recommended value)
    Stable time1 to 30s1 to 30s
    Fluctuation0.1~1mV0.1~1mV

    Table 6

    5.4.4 pH parameter setting
    5.4.4.1 pH standard solution group management
    The meter provides various Standards Group including GB, DIN, NIST and USA. And allows the user to prepare the customized Standard groups.
    Standard Solution Groups

    GroupsContents
    GB1.68pH, 3.56pH, 4.00pH, 6.86pH, 7.41pH, 9.18pH, 12.46pH
    DIN1.68pH, 2.00pH, 3.56pH, 3.78pH, 4.01pH, 6.87pH, 7.00pH, 7.42pH, 9.18pH, 10.01pH, 12.45pH
    NIST1.68pH, 4.01pH, 6.86pH, 7.00pH, 7.42pH, 10.01pH, 12.47pH
    USA1.68pH, 4.01pH, 7.00pH, 10.01pH

    Table 7

    Figure 7
    Selection of standard groups and standard solution
    Usually we use the pH value corresponding to 25.0°C to mark the pH standard buffer solution, such as NIST 7.00pH standard solution, which means the standard pH buffer solution 7.00pH, and it is 7.00pH at 25.0°C.
    After selecting the standard solution group, we need to select the standard buffer solution used for calibration from the standard solution group. The instrument supports up to 5-point calibration, that is, up to 5 standard solutions can be selected. Since the pH values of multiple standard buffer solutions in the standard solution group may be very close, to ensure that the instrument can correctly identify the standard buffer solution, will limit the selection of standard solutions with neighboring pH values. The check mark indicates the currently used standard solution group and the corresponding standard solution.
    TIPS:
    If the selected standard solution group is different from the pH standard buffer solution used, it will lead to wrong calibration results.

    5.4.4.2 Manual standard solution identification
    In some special cases, it is necessary to use some non-standard pH buffer solutions, or use two very close pH standard buffer solutions for electrode calibration. In this case, the manual standard solution identification function can be used. When set to "manual identification", the pH value of the current standard solution can be input during and used for electrode calibration.

    5.4.4.3 Resolution settings
    The pH measurement resolution of the instrument is adjustable.
    pH resolution: 0.01pH and 0.1pH.
    mV resolution: 0.1 mV and 1 mV.
    5.4.5 pX/ISE parameter settings
    5.4.5.1 Ion mode selection
    Ion mode corresponds to pX, ion concentration measurement. The instrument supports conventional ion modes and user-defined ion modes. The instrument provides a variety of commonly used ion modes such as: F-, Cl-, Br-, I-, NO3-, BF4-, NH4+, K+, Na+, Ca2+, Cu2+, Pb2+, Ag+ and etc., which are convenient for use. Users can directly measure the concentration of the corresponding ions as long as they are equipped with the corresponding ion selective electrode and reference electrode.
    The instrument allows the creation of custom ions, up to 6 types. Press the "Create" key, enter the ion name (maximum 8 characters), then enter the molecular weight (molar mass), and select the ionic valency.

    Figure 8
    Manage and select ion modes

    5.4.5.2 Select measurement mode
    BMET-503 pH/on meter supports direct reading concentration method to measure ion concentration, also known as the standard curve method, is the most commonly used method for measuring ion concentration. This method establishes a linear relationship between the ion concentration and the electrode potential according to the Nernst formula:

    In the formula:
    Ex~ Equilibrium potential of the sample to be tested, in mV,
    E0~ Zero potential value, in mV,
    S ~ Electrode slope (%),
    Cx~ The concentration value of the sample to be tested, in mol/L,
    Cb~ Blank concentration value, in mol/L.
    By calibrating with a known concentration standard solution, the slope and zero potential value can be obtained, and a calibration curve can be established. When measuring an unknown sample, the corresponding concentration value can be read on the calibration curve through the measured potential value. The direct reading method has a fast measurement speed and is suitable for a large number of samples' fast measurement.
    The result unit, blank concentration value, pX resolution and mV resolution can be set before measurement. Among them: pX measurement supports two resolutions, 0.01pX and 0.1pX, mV supports 0.1 mV and 1 mV.

    5.4.6 Temperature Parameter Settings
    The temperature unit of the meter is selectable in °C and °F.
    Temperature compensation mode: ATC and MTC.
    ATC means automatic compensation.
    MTC means manual compensation. It allows user to input the temperature.

    5.4.7 Data Management Settings
    5.4.7.1 Sample ID setting
    The instrument supports three setting methods of Sample ID: Auto sample ID in number order, Auto sample ID in time order, and manual sample ID.
    • ID in number order: The sample ID No. is increasing with series number, allow to set ID digits (3 to 5 digits) and initial sample ID.
    • ID in time order: The sample ID No. is increasing with sample measuring time. Format, Year/Y, Month/M, Day/D, Hour/H, Minutes/M, Second/S
    • Manual sample ID: Manually set the sample ID No when saving or printing data.
    5.4.7.2 Autosave setting
    When this function is enabled, the meter saves the results when the reading is stable in the auto-reading and interval timed reading mode.
    5.4.7.3 Overwrite setting
    The meter provides 500 sets of measurement results storage space. When this function is enabled, the results data that exceeds capacity will overwrite the old results data.
    5.4.8 Output option
    Output the measurement results by selecting the data format.
    The data formats are GLP, STD, and Custom.
    5.4.9 User ID Settings
    Allow to set the user ID.
    5.4.10 System Parameter Settings
    5.4.10.1 System time settings
    Settings of system time and date.
    5.4.10.2 Buzzer settings
    Users can set the key sound by this setting.
    5.4.10.3 Backlight settings
    Users can adjust the screen brightness by this setting.
    5.4.10.4 Automatic shutdown settings
    The meter provides auto shutdown function. When the meter is not using and set the auto shutdown, the meter switches off automatically. There are six options: off, 1min, 2min, 3min, 5min, 10min, 15min, 20min, 30min, and 60 min.
    5.4.10.5 Reset settings
    The meter supports "Reset Measure Parameter" and "Reset All".
    "Reset Measure Parameter" will reset measurement parameters to factory default and reset the calibration data to factory default calibration data.
    "Reset All" will reset user ID and measurement parameters to factory default, and delete all results.
    5.4.10.6 Software version
    It shows software version information.

    5.5 pH Measurement

    5.5.1 Calibration preparation
    The electrode slope and zero potential of pH electrodes drift slightly over time. To accurately measure pH, it is recommended to calibrate the pH electrode before use, the instrument supports 1-5 points calibration.
    One point calibration is a calibration process with a single standard solution, commonly applied in a quick test. The calibration slope is 100% in here.
    Two-point calibration is to use two pH standard buffer solutions to calibrate the electrode, and construct a linear calibration curve through two points. Two-point calibration is the most commonly used calibration method, and it is usually recommended that the pH value of the solution to be measured lies between the two standard buffer solutions. Two-point calibration can improve pH measurement accuracy.
    Multi-point calibration is a calibration process with more than one standard solution. It is recommended to calibrate between two standard buffer solutions at the pH of the solution to be tested. Multi-point calibration covers a wider measurement range for accurate pH measurement. Before starting calibration, please prepare one or more pH standard buffer solutions.

    5.5.2 pH electrode calibration
    The calibration process is as follows:
    1. Setting.
    1) Set the parameters (e.g. pH).
    2) Select NIST standard solution group, and check pH 4.01, pH 7.00 and pH 10.01 three standard solutions.
    3) Set the Auto Mode recognition.
    2. Press the F2"Calibrate"-"pH Calibration".
    3. Put the cleaned electrode into pH 4.01 standard solution.
    4. Wait for the instrument to display "Auto Mode Matched", or the instrument reading is stable, press the F4 "Start".
    5. If only 1-point calibration is required, after 1-point calibration is completed, press the "Enter" key to complete the calibration.
    6. If multi-point calibration is required, please replace the pH7.01 and pH10.01 standard buffer solutions. After cleaning the electrode, put the electrode into the standard solution. After the instrument recognizes it successfully, the instrument reads stably, press the F4"Next Point" to complete the calibration.
    7. After completing the calibration, press the "Enter" key to complete the calibration, save the calibration results and end the calibration, directly enter the start interface. If the checked standard solution group is 5, automatically end the calibration after five points of calibration.

    Figure 9
    pH electrode calibration

    5.5.3 pH measurement
    The measurement process is as follows:
    1. Setting.
    1) Set the parameters (e.g. pH).
    2) Set the reading mode (e.g., continuous reading, auto-reading, or timed format).
    2. Put the electrode into test solution under test.
    3. In the idle status, press F4 "Measure" to enter into measurement status.
    4. When the reading is stable, press "Enter" to read the results.
    5. Press the "Save" to save the measurement results.
    6. Press the "Output" to print the measurement result when connect to the printer.
    7. Between measurements, stored pH electrode in distilled or deionized water.
    8. After measurement, rinse the pH electrode with deionized water thoroughly.

    Figure 10
    pH measurement information
    TIPS:
    ➤ The measurement end of the electrode should well be immersed into the sample solution.
    ➤ For high accuracy measurement, make sure the measurement is carried out at the lab with constant temperature and pressure.
    ➤ If the two temperatures are different, it is recommended to use a pH combination electrode with temperature compensation or use a separate temperature electrode for automatic temperature compensation. Or use a thermometer to measure the temperature of the current solution, and manually set the temperature for manual compensation.

    5.6 Ion measurement

    5.6.1 Preparation
    The slope and zero potential value of the ion electrode will change with time, so the ion electrode needs to be calibrated before use, and the instrument supports up to 5-point calibration. For the specific use of the electrode, please refer to the electrode manual.
    5.6.1.1 Ion-selective electrode
    The ion-selective electrode is based on the ion-selective membrane, which can be divided into single crystal membrane, salt membrane, glass membrane and PVC ion-selective membrane. Ion-selective electrodes usually have single electrodes and composite electrodes. Single electrode can be used with different reference electrodes, and has better measurement performance for some low-concentration ions. Composite electrodes are more convenient and
    simpler in the operation. The meter requires the composite electrode. You could be flexible to choose according to the requirements.
    5.6.1.2 Ionic strength adjustment buffer
    The use of ion electrodes to measure ion concentration requires the addition of ionic strength adjustment buffer.
    The ionic strength of a solution has an important influence on the measurement of ion concentration. On the one hand, the ion-selective electrode directly measures the activity of the ion, α = γc. Wherein, α is the activity of the ion, γ is the activity coefficient of the ion, and c is the ion concentration. Usually, the activity coefficient γ is affected by the ionic strength in the solution. By adding ionic strength adjustment buffer to the standard solution and the test solution, the measured solution has a similar ionic strength to the standard solution, thereby having a similar activity coefficient γ. On the other hand, is a solution with low ionic strength, the potential of the reference electrode will show instability. The addition of the ionic strength adjustment buffer can help stabilize the reference electrode.
    Various ion measurement needs various ionic strength adjustment buffer. Common ionic strength adjustment buffers are recommended in the following table
    Recommended ionic strength adjustment buffer

    Ion categoryIonic strength adjustment buffer
    Na +0.2 mol/L diisopropylamine
    F -0.1 mol/L NaCl or TISAB
    Cl -0.1 mol/L KNO 3
    Br -0.1 mol/L KNO 3
    I -0.1 mol/L KNO 3
    Ag +0.1 mol/L NaNO 3
    Cu 2+0.1 mol/L NaNO 3
    Pb 2+0.1 mol/L KNO 3
    S 2-0.1 mol/L KNO 3
    K +0.05 mol/L MgAc 2
    Ca 2+0.1 mol/L KCl
    NO 3 -0.1 mol/L NaH 2 PO 4
    BF 4 -0.1 mol/L Na 2 SO 4
    ClO 4 -0.1 mol/L NaCl

    Table 8
    * The final concentration of the ionic strength adjustment buffer in the standard or sample.

    5.6.1.3 Standard solutions preparation
    The best way to prepare standards is to use serial dilutions. Sequential dilution refers to diluting an initially prepared standard using a volumetric flask to obtain a second standard. Dilute the second standard to prepare a third standard. And so on until the required standard solution is obtained.
    In general, the concentration between two adjacent levels is a 10-fold relationship.

    5.6.1.4 Activation of the ISE electrodes
    When the electrode is used for the first time or has not been used for a long time, an activation is recommended. The electrode has better measurement performance after activation.
    Ion electrode activation solution and activation time recommendation

    Ion categoryActivation solutionActivation time
    Na +10 -3 mol/L NaCl2h
    F -10 -3 mol/L NaF2h
    Cl -10 -3 mol/L KCl2h
    Br -10 -3 mol/L NaBr2h
    I -10 -3 mol/L NaI2h
    Ag +10 -3 mol/L AgNO 32h
    Cu 2+10 -3 mol/L Cu(NO 3 ) 22h
    Pb 2+10 -3 mol/L Pb(NO 3 ) 22h
    S 2-10 -3 mol/L AgNO 32h
    K +10 -3 mol/L KCl2h
    Ca 2+10 -3 mol/L CaCl 22h
    NO 3 -10 -3 mol/L NaNO 32h
    BF 4 -10 -3 mol/L NaBF 42h
    ClO 4 -10 -3 mol/L NaClO 42h

    Table 9
    TIPS:
    The activation time may variously be based on various activation solutions. See the ion-selective electrode manual for specifications.

    5.6.1.5 Stirrer setting
    The flow state of the solution influences the electrode potential of the ion-selective electrode. To improve the stability and repeatability of the measurement, it is recommended to use a stirrer to keep the flow rate of the solution stable during calibration and measurement.
    5.6.2 pX/ISE Calibration

    Figure 11
    pX/ISE calibration information
    The pX/ISE calibration process is as follows:
    1. Add an appropriate amount of standard solution (usually 100 ml) to the beaker, then add ionic strength adjustment buffer. Adjust the stirring speed of the solution for measurement.
    2. Press the F2 "Calibrate"-"pX Calibration".
    3. Put the cleaned electrode into standard solution.
    4. Press the F2 "STD Value" to input the standard value of the standard solution.
    5. Wait for the reading is stable, press the F4 "Start".
    6. If only 1-point calibration is required, after 1-point calibration is completed, press the "Measure" to complete the calibration.
    7. If choosing multi-points calibration (up to 5), press "Next Point" to repeat the operation.
    8. If the checked standard solution group is 5, automatically end the calibration after five points of calibration.
    TIPS:
    ➤ Please recalibrate for an unexpected measurement result.
    ➤ A room temperature test solution is recommended.
    ➤ It is recommended to calibrate from low concentration to high concentration standards.

    5.6.3 pX/ISE Measurement
    Select the ion measurement methods by user needs. In general, when direct-reading method is using for ion concentration measurement and pX measurement.
    The measurement process is as follows:
    1. Setting.
    1) Set the parameters (e.g., pX).
    2) Set the ion mode (e.g. F-).
    3) Set the direct Reading as concentration meas mode.
    4) Set the concentration unit (e.g. ppm).
    5) Set the reading mode (e.g., continuous reading, auto-reading, or timed format).
    2. Add an appropriate amount of standard solution (usually 100 ml) to the beaker, then add ionic strength adjustment buffer. Adjust the stirring speed of the solution for measurement.
    3. In the idle status, press F4"Measure" to enter into measurement status.
    4. When the reading is stable, read the results.
    5. Press the "Save" to save the measurement results.
    6. Press the "Output" to print the measurement result when connect to the printer.
    7. Between measurements, stored ISE electrode in distilled or deionized water.
    8. After measurement, rinse the ISE electrode with deionized water thoroughly.

    Figure 12
    PX/ISE measurement information
    TIPS:
    Different ISE probes have different potential values in a blank solution. If the blank potential is away from the reference value, the user can do an activation to improve the performance of electrodes. If the electrode still does not meet the requirements, a new electrode is quite considerable.

    5.7 Data Management

    Press "Data" to view the detail of results.
    The meter stores the measurement results independently according to the measured parameters. The meter provides data Storage 500 sets for each parameter (pH/mV/Temp).
    The user can press "Delete" into the delete menu. It allows users to select the parameter data or all data to delete.
    The user can view the data filter by parameter, locate No. or stored date. By the filter setting, press "Start Search" to look up the data. The filter data shows in a graph. Press "←" and"→" to choose data. User can choose one and press "Enter" key to see the detail result. Users can press "Delete" to delete the current result. Press "Output" to select the output data. The format supports output the current result, output matched result and output all result.

    Figure 13
    Results setting view

    Figure 14
    Review stored results by graph
    TIPS:
    ➤ In order to ensure the correct use of the instrument and avoid burning the instrument and causing unnecessary losses to you, please turn off the power of the instrument and printer before connecting the printer.
    ➤ The communication baud rate of the meter is always 9600bps, the default setting is 8 data bits, one start bit, one stop bit, no parity.
    Output format is approximately as follows:
    ****************************************
    Report Title
    ----------------------------------------
    Measure Time:2021/01/19 12:27:28
    Operator: Operator 1
    Model: BMET-503 pH/Ion Meter
    Serial Number:
    SW Version: Ver 1.00
    ----------------------------------------
    ............................MATCHED INFO
    Stored Num: 28
    Matched Num: 1
    Stored No.: 15

    ..............................CALIB INFO
    Calib Operator: REX Team
    Calib Time: 2020/05/13 08:30:00
    Calib Num: 3
    ............................CALIB RESULT
    STD 1: 4.00pH 177.3mV 25.0c
    STD 2: 6.86pH 8.0mV 25.0c
    STD 3: 9.18pH -129.1mV 25.0c
    pH Slope 1: 100.00%
    pH E0 1: 0.0mV
    pH Slope 2: 100.00%
    pH E0 2: 0.0mV
    ..............................BRIEF INFO
    Reading Mode: Timed Reading
    Stable Type: Medium
    Temp Comp Type: ATC
    .............................SAMPLE INFO
    Sample ID: Sample 1
    ..................................RESULT
    Result: 7.00pH
    Signal Value: -0.0mV
    Temp Value: 25.0c
    ----------------------------------------
    ----------------------------------------

    6. Maintenance/Troubleshooting

    6.1 Meter Maintenance

    The correct use and maintenance of the instrument can ensure the accurate and reliable performance of the instrument. Additionally, exposure to chemicals or harsh use environments can affect performance.
    The pH/pX electrode socket has a protective plug, when the meter is not in use, please insert the protective plug into the pH/pX socket.
    • If the meter is not used for a long time, please disconnect the power supply.
    • The electrode socket of the instrument must be kept clean and dry, and should not be in contact with acid, alkali, and salt solutions.
    • Keep the meter and accessories clean and away from acids, alkalis, and any corrosive solutions/gases.
    • Users can clean the meter surface with clean waters and detergent.
    • When the meter is transported, please follow the instructions:
    • please remove all connected cables.
    • Please remove the electrode holder.
    • Please use original packaging in the long-distance transport to avoid damage.

    6.2 Electrodes Maintenance

    For more detailed information, please refer to the electrode instruction manual.

    6.3 Troubleshooting


    PhenomenonProbable reasonsSolutions
    1. No DisplayNot powered on.
    Damage to the meter.
    Connect the adapter and press the power key to turn it on. Replace or repair as required.
    2. Incorrect mV measurement is1. The electrode is out of service life
    2. The electrode plug is in poor contact
    1. Replace the electrodes
    2. Connect the protection plug, if the potential is not 0mV, please contact the after-sales service.
    3. Incorrect pH measurement1. Refer to as 2.2
    2. Refer to as 2.2
    3. The electrodes are not calibrated or are calibrated incorrectly
    1. Refer to as 2.2
    2. Refer to as 2.2
    3. Recalibrate the electrode or replace the standard solution
    4. Incorrect pX/ISE measurement1. Refer to as 2.2
    2. Refer to as 2.2
    3. The electrodes are not calibrated or are calibrated incorrectly
    4. Incorrect ISE probe
    1. Refer to as 2.2
    2. Refer to as 2.2
    3. Recalibrate the electrode or replace the standard solution
    4. Buy correct ISE probe. Add ionic strength adjustment buffer.

    Table 10
    If the meter still does not work, please contact your local dealer for further assistance.

    7. Technical Supports

    Accessories
    Please refer to the accessories table for purchasing recommendations.
    Meter accessories

    NameDescription
    E-301-QC 3 in 1 pH composite electrodepH Measurement Probe
    PF-2-01 Fluoride ion electrodeMeasure the fluoride ion content
    232-01 Reference electrodeUse with ion electrode
    T-818-Q Temperature electrodeMeasure temperature value
    REX-5 Electrode standPlace electrodes during measurement
    pH 4.01/7.00/10.01 standard sachetsTo prepare the standard

    Table 11

    8. Appendixes

    Appendix 1
    pH-Temperature Relationship Table of pH Standard Solutions
    Temperature(°C)1.684.017.0010.01
    51.674.007.0910.25
    101.674.007.0610.18
    151.674.007.0410.12
    201.684.007.0210.06
    251.684.017.0010.01
    301.684.016.999.97
    351.694.026.989.93
    401.694.036.979.89
    451.74.046.979.86
    501.714.066.979.83